(2-Aminophenyl)methyldiphenylphosphonium iodide
نویسندگان
چکیده
The asymmetric unit of the title compound, C(19)H(19)NP(+)·I(-), contains two tetra-alkyl-phospho-nium cations and two I(-) anions. The P atoms are four-coordinated in distorted tetra-hedral configurations by three phenyl and one methyl C atoms. There are weak intra- and inter-molecular N-H⋯I contacts.
منابع مشابه
Bis[(2-aminophenyl)methanol-κ2 N,O]bis(nitrato-κO)zinc(II)
In the title compound, [Zn(NO(3))(2)(C(7)H(9)NO)(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa-hedral geometry by two N atoms and two O atoms from two (2-amino-phen-yl)methanol ligands and two O atoms from two monodentate nitrate anions. Inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds stabilize the crystal structure.
متن کامل(2E)-1-(4-Aminophenyl)-3-(2,4-dichlorophenyl)prop-2-en-1-one
The title compound, C(15)H(11)Cl(2)NO, is approximately planar (r.m.s. deviation = 0.062 Å) and contains a single C=C double bond in a trans (E) configuration. The crystal packing is stabilized by intermolecular N-H⋯N and N-H⋯O inter-molecular hydrogen bonding.
متن کامل2-(4-Aminophenyl)-1,3-benzoxazole
In the title mol-ecule, C(13)H(10)N(2)O, the dihedral angle between the benzoxazole ring system and the benzene ring is 11.8 (1)°. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯N hydrogen bonds and π⋯π inter-actions [centroid-centroid distance = 3.6560 (15) Å] to form a two-dimensional network.
متن کاملBis[(2-aminophenyl)methanol-κ2 O,N]bis(nitrato-κO)manganese(II)
In the title compound, [Mn(NO(3))(2)(C(7)H(9)NO)(2)], the Mn(II) atom (site symmetry 2) is coordinated by two N,O-bidentate (2-amino-phen-yl)methanol ligands and two monodentate nitrate anions in a distorted cis-MnN(2)O(4) octa-hedral coordination geometry. In the crystal, N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds help to establish the packing.
متن کامل2-(1-Adamantyl)-1-(3-aminophenyl)ethanol
In the crystal structure of the title compound, C(18)H(25)NO, mol-ecules are linked via O-H⋯N hydrogen bonds, forming chains parallel to the c axis. Additional weak N-H⋯O inter-actions stabilize the crystal packing. The adamantane cage consists of three fused cyclo-hexane rings in almost ideal chair conformations, with C-C-C angles in the range 107.9 (10)-111.3 (11)°.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008